MME312 : الديناميكا الحرارية 2

القسم العلمي

قسم هندسة المواد والمعادن

البرنامج الدراسي

بكالوريوس في هندسة مواد ومعادن

نوع المقرر

إجباري

الوحدات

03

الاسبقيات

GS102

نظرة عامة

-Behavior of gases: gas mixtures of ideal gases. the thermodynamic treatment of imperfect gases, deiation from ideality and equations of state and the van der walls gas.

 

-Reactions invocving gases: reaction equilibrium in a gas mixture and the equilibrium constant.

The effects of temperature and pressure on the equilibrium constant. Reaction equilibrium in the system: SO2(g)-SO3(g)-O2(g).Equilibrium in H2O-H2 and CO2-CO mixtures. Gaseous reaction equilibrium and fugacity.

 

-Reactions inoling pure condensed phases and a gaseous phase: Free energy variation with temperature, the Ellingham diagrams, effects of phase diagram, the oxides of carbon and graphical representation of equilibrium in the system metal-oxygen- carbon.

 

-Behaior of solutions: Raoult's law and Henry's law, the activity of a component in solution,

the Gibbs-Durham equation, free energy of solution, properties of Raoultian ideal solutions, and non- ideal and regular solutions.

 

-Free energy-composition and phase diagrams of binary systems: Free energy and activity, free energy of regular solutions. phase diagrams, free energy, and activity.

 

-Reaction equilibrium in systems containg components in condensed solutions:

 Reaction equilibrium criteria in systems containing components in condensed solution, alternative standard states, the Gibbs phase rule, binary systems involving compound formation, the solubility of gases in metals, the formation of oxide phases of rariable composition, graphical representation of phase equilibrium, solutions containing several dilute solutes, tabular representation of thermodynamic data and the free energy function and analysis of experimental data of the second and third law methods.