-Behavior of gases: gas mixtures of ideal gases. the thermodynamic treatment
of imperfect gases, deiation from ideality and equations of state and the van
der walls gas.
-Reactions invocving gases: reaction equilibrium in a gas mixture and the
equilibrium constant.
The effects of temperature and pressure on the
equilibrium constant. Reaction equilibrium in the system: SO2(g)-SO3(g)-O2(g).Equilibrium
in H2O-H2 and CO2-CO mixtures. Gaseous
reaction equilibrium and fugacity.
-Reactions inoling pure condensed phases
and a gaseous phase: Free energy variation with
temperature, the Ellingham diagrams, effects of phase diagram, the oxides of
carbon and graphical representation of equilibrium in the system metal-oxygen-
carbon.
-Behaior of solutions: Raoult's law and Henry's law, the activity of a component
in solution,
the Gibbs-Durham equation, free energy of solution,
properties of Raoultian ideal solutions, and non- ideal and regular solutions.
-Free energy-composition and phase
diagrams of binary systems: Free energy and activity, free energy of regular
solutions. phase diagrams, free energy, and activity.
-Reaction equilibrium in systems
containg components in condensed solutions:
Reaction
equilibrium criteria in systems containing components in condensed solution,
alternative standard states, the Gibbs phase rule, binary systems involving
compound formation, the solubility of gases in metals, the formation of oxide
phases of rariable composition, graphical representation of phase equilibrium, solutions
containing several dilute solutes, tabular representation of thermodynamic data
and the free energy function and analysis of experimental data of the second
and third law methods.