CH623 : Organometallic chemistry

Department

Department of Chemistry

Academic Program

Master in inorganic chemisty

Type

Compulsory

Credits

02

Prerequisite

CH622CH6632

Overview

This course aims to:1) Familiarity with the general concepts and principles of metal compounds and their membership, and introducing the student to the types of alkyl and aryl metals of dinuclear compounds and alkyl bridge groups.2) Explanation of the nature of metal compounds, basic and transitional metal memberships, classification principles, preparation methods, and metal-carbon bridge bonds.3) Introducing the student to oxidative addition reactions for a group of transition metals and insertion reactions4) Comparison between different types of reactions, homogeneous and heterogeneous catalysis and their applications, and identification of carbonyl complexes by (X-ray and IR).

Intended learning outcomes

a. Knowledge & understandingA.1 Introducing the student to new theoretical methods and developing methods for preparing organic metal compounds in an applied formula as catalysts.A.2 Introducing students to methods of preparing organic compounds by homogeneous catalysts.A.3 Giving the student a modern scientific addition in this field and how to diagnose various metal and organic complexes by means of a group of devices such as (X-ray, IR and H, C13NMR).A.4 Its importance as catalysts in the field of petrochemical industries.B. Mental skillsB.1 The ability to reproduce information on metal and organic compounds.B.2 The ability to classify metallic and organic compounds.B.3 The ability to present and discuss data and information in a sound scientific manner.B.4 The ability to practice creative and analytical thinking skills by analyzing and interpreting the results and discussing them after diagnosing the prepared materials.c. Practical & professional skillsC.1 Giving students the basic concepts of the chemistry of metal compounds and the organic elements of basic and transitional elements, which makes them more understanding and knowledge of the importance of these elements in our lives.C.2 The ability to classify the various metal and organic compounds in terms of the type of metal and the types of connections (such as carbonyls, phosphines, nitrosyl, alkenes, arenes, carbenes and carbynes)C.3 Develop students' ability to be self-reliant in solving problems they encounter while studying this course and other courses related to this course.C.4 Follow-up skill in arranging and organizing homogeneous and heterogeneous stimulus.Dr. Generic and transferable skillsD.1 Know the basic concepts in the preparation and reactions of organic metals.D.2 The ability to analyze, prepare and understand the processes used in the preparation of organic metal compounds.D.3 Understand the application of knowledge gained in their field of specialization at a professional level and develop the use of stimuli in industry.D.4 Acquisition of skills to determine the best strategy for the preparation of unknown compounds using organometallic chemistry.

Teaching and learning methods

• Lectures.• Problem solving duties.• A quarterly report on the subject of inorganic interactions mechanics.• Discuss the report.

Methods of assessments

First written exam 25%Second written exam 25%final exam 50%

1. محتوى المقرر (Course contents)

الموضوع العلمي

عدد الساعات

محاضرة

معمل

تمارين

مناقشة

مذاكرة مستقلة

عدد الاسابيع

Metal alkyl and aryl types(binuclear with metal-metal bonds)

3

3

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1

Polymeric with bridging alkyl groups and metalocyclic complexes

6

6

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2

Compounds with transition metal carbon multiple bonds

3

3

--

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1

Metal compounds of heterocycles

3

3

--

--

--

--

1

5 and 6 electron metal compounds

3

3

--

--

--

--

1

Elimination addition reactions Ni, Pd and Pt

6

6

--

--

--

--

2

Oxidition addition reactions of Rh, I, Fe, and OS

6

6

--

--

--

--

2

Homogeneous catalysis cyclometallation

6

6

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--

--

2

Insertion reactions

3

3

--

--

--

--

1

Metal carbonyl spectra (IR and X-ray)

3

3

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--

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1